Wednesday evening, August 24, 2022, we will know which 32 teams will compete in this season's Champions League. Six tickets are still up for grabs and these will be distributed between the remaining teams from the preliminary rounds on Tuesday and Wednesday. Tuesday night we see Benfica in action, among others. The Portuguese got an excellent result against Dinamo Kiev last week, and will be looking to finish the job at home. On Wednesday it is PSV's turn to try and qualify for the first time in four years. All matches and odds are listed below.
Fixtures decisive Champions League play-offs
| Match | Odd (1 X 2) | Outcome |
| Tuesday | ||
| Benfica - Dinamo Kiev | 1.33 - 5.25 - 8.00 | 2-0 |
| Red Star Belgrade - Maccabi Haifa | 1.75 - 4.00 - 4.20 | 2-3 |
| Viktoria Plzen - Qarabag | 2.05 - 3.10 - 3.80 | 0-0 |
| Wednesday | ||
| Dinamo Zagreb - Bodo Glimt | 1.85 - 3.80 - 3.80 | 0-1 |
| PSV - Rangers FC | 1.75 - 3.75 - 4.50 | 2-2 |
| Trabzonspor - FC Copenhagen | 2.05 - 3.75 - 3.40 | 1-2 |
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